Suggested Reading
  • Chapter Sixteen: Thermodynamics (p. 749-778)
  • Chapter Seventeen: Electrochemistry (p. 791-808, 816-820)
  • Chapter Twenty-Two: Organic and Biological Molecules (p. 997-1015)
Learning Objectives
  • Compare the absolute entropies, S°, of elements and compounds
  • Perform calculations with entropy S° and ∆S°
  • Perform calculations with free energy, ∆G°f
  • Calculate the value of K from thermodynamic values such as ∆G°
  • Identify and compare the two types of electrochemical cells: galvanic and electrolytic
  • Draw and label a galvanic cell, including labeling the electrodes, the flow of electrons, and the flow of ions
  • Write half-reactions and determine which reaction occurs at the anode and which reaction occurs at the cathode
  • Give the line notation for a galvanic cell or write a balanced redox from the given line notation
  • Calculate the cell potential for a galvanic cell and an electrolytic cell
  • Determine if a reaction is spontaneous from its cell potential
  • Calculate the cell potential under nonstandard conditions when the solutions are not 1M, using the Nernst equation
  • Determine the strengths of oxidizing agents and reducing agents
  • Draw and label an electrolytic cell
  • Determine the reactions which occur at the anode and the cathode during electrolysis
  • Perform stoichiometric calculations involving electrolysis
  • Know how to write formulas, names, and structures for organic compounds including alkanes, alkenes, alkynes, cyclic compounds and compounds with functional groups
Lecture Concepts
  • Thermodynamics
    • Thermodynamic Laws
    • Entropy
    • Spontaneity Processes & Free Energy
      • Connection to equilibrium & cell potential
      • Electrochemistry
      • Balancing Redox Equations
      • Galvanic Cells
        • Cell Potential
        • Nernst Equation
      • Electrolytic Cells
        • Batteries
  • Introduction to Organic Chemistry
    • Nomenclature

Problem Set #8
  • Chapter 16 → 19, 27, 33, 37, 45 (a, c), 55, 57
  • Chapter 17 → 15, 16, 25, 27, 31 (only 25 part), 35, 37, 45, 55, 65 (only 25 part), 71, 77, 79 (a-c)
  • Chapter 22 → 17, 21, 25, 31, 47

Assignments